Selection Guide – PTFE & Filled Grades

PTFE (Polytetrafluoroethylene), commonly known as Teflon™, is a high-performance fluoropolymer with exceptional chemical inertness, high-temperature resistance, and a low coefficient of friction. Selecting the appropriate PTFE grade depends heavily on the specific application requirements, including operating conditions, desired properties, and potential exposure to chemicals or other environmental factors.

Key factors influencing PTFE selection

Operating conditions:
-Consider the temperature, pressure, speed, load, and media the PTFE product will encounter.
-PTFE offers a wide operating temperature range, typically from -200°C to +260°C (-328°F to +500°F). However, specific grades may have different temperature limitations, especially when subjected to high pressure or dynamic loading.

Desired properties:
-Identify the crucial properties needed for your application. These could include:

Chemical resistance:
-PTFE is highly resistant to most chemicals, but some fillers may affect compatibility with specific media.

Mechanical strength:
-Virgin PTFE is relatively soft and prone to cold flow (creep). Fillers such as glass fiber, carbon, or bronze can enhance its mechanical strength, hardness, and wear resistance.

Wear resistance:
-Filled PTFE grades are often preferred in dynamic sealing or bearing applications where improved wear resistance is crucial.

Frictional properties:
-PTFE's exceptionally low coefficient of friction is a key advantage for non-stick applications or where reduced friction is desired.

Electrical properties:
-PTFE boasts excellent electrical insulation properties, including high dielectric strength and a low dielectric constant.

Dimensional stability:
-The choice of PTFE grade and manufacturing process can significantly impact dimensional stability, particularly under varying temperatures and loads.

Biocompatibility:
-Virgin and ePTFE are non-toxic and biocompatible, making them suitable for use in food, pharmaceutical, and medical applications.

Common PTFE grades and their applications

Virgin PTFE:
-Offers excellent chemical resistance, outstanding electrical properties, and good flexibility.
-It is suitable for general applications, including gaskets and bellows, especially in food and medical contact situations.

Chemically Modified PTFE:
-Provides less creep, improved permeation resistance, smoother surfaces, and better high voltage insulation compared to virgin PTFE.
-It is suitable for pumps, diaphragms, ball valve seats, and vessel linings.

Glass Filled PTFE:
-Increases compressive strength, enhances wear resistance under load, and reduces permanent deformation.
-Applications include ball valve components and Bridge Bearing Pads.

Carbon/Coke Filled PTFE:
-Offers high compressive strength, improved wear resistance, and better thermal/electrical conductivity.
-It is ideal for rider and piston rings of air compressors.

Graphite Filled PTFE:
-Provides high compressive strength, improved wear resistance and frictional properties, and good chemical resistance.
-It is commonly used for shaft bearings and in high-speed chemical pumps.

Bronze Filled PTFE:
-Exhibits excellent wear resistance, high compressive strength, very low cold flow, and good thermal/electrical conductivity.
-It finds applications in wear strips, machine tool liners, and hydraulic seals.

Expanded PTFE (ePTFE):
-Possesses a unique microstructure that provides multi-directional strength, high porosity, and exceptional conformability, making it ideal for sealing irregular or fragile flanges, even with low bolt loads.
-It is also highly creep and cold flow resistant and retains the universal chemical resistance of virgin PTFE.

Manufacturing processes and considerations

-PTFE is processed using methods like compression molding, ram extrusion, isostatic molding, skiving, and machining due to its high melt viscosity.
-The chosen manufacturing method impacts the final product's properties, dimensional accuracy, and suitability for specific applications. For example, compression molding allows for a wide range of shapes, while ram extrusion is well-suited for producing long lengths of rods and tubes.

Standards Used in the PTFE Industry
1. PTFE Sheets & Plates
Standard Description / Scope Importance
ASTM D4895 / ISO 12086Defines properties of suspension PTFE resin used for moulding sheets.Ensures base material consistency and quality.
ASTM D1457Specification for moulded and extruded PTFE materials.Maintains mechanical strength, density, and purity of sheets.
AMS 3663Aerospace-grade moulded PTFE sheets.Guarantees dimensional stability and reliability under high load/temperature.
DIN 7725 / EN 12086European classification of PTFE sheets.Enables export compliance and consistency in EU markets.
ASTM D4892Test for density and uniformity.Confirms sheet homogeneity and absence of voids.

Area of Application: Used for gaskets, slide plates, electrical insulation. Standards ensure flatness, thickness accuracy, chemical purity, and wear resistance.

2. PTFE Rods & Bars
StandardDescription / ScopeImportance
ASTM D4895 / AMS 3660PTFE suspension resin & aerospace-grade moulded rod specification.Ensures machinability and mechanical strength.
ASTM D1457Specification for extrusion and moulding material.Defines consistent extrusion properties and surface finish.
ISO 12086-1Classification of PTFE rods & extrusions.International harmonization of grades and properties.
ASTM D638Tensile testing.Confirms mechanical strength before machining into parts.

Area of Application: Used for machined parts, seals, valve seats, and bearings. Standards ensure uniform mechanical performance, density, and surface quality.

3. PTFE Tubes & Linings
StandardDescription / ScopeImportance
ASTM D4895 / AMS 3662Ram extrusion-grade PTFE materials.Ensures proper extrusion and wall thickness integrity.
ASTM D3294Specification for sintered PTFE tubing.Defines dimensions, dielectric strength, and mechanical properties.
ASTM D543Resistance of plastics to chemicals.Ensures chemical stability for corrosive fluid handling.
IEC 60684Electrical insulation sleeving — PTFE.Sets dielectric and flame resistance for tubing in electrical use.

Area of Application: Used in chemical piping, wire insulation, linings. Standards ensure uniform wall thickness, dielectric strength, chemical inertness, and temperature resistance.

4. PTFE Seals, Gaskets & Valve Seats
StandardDescription / ScopeImportance
ASTM D1457 / D4895PTFE base material specifications.Ensures seal material purity and compression performance.
ASTM D695Compressive properties of plastics.Determines deformation under sealing loads.
ASTM D1894Coefficient of friction.Evaluates low-friction surface behaviour in dynamic seals.
ISO 15527Tensile creep and rupture.Measures long-term sealing performance under stress.
FDA 21 CFR 177.1550Food-contact compliant PTFE.Ensures safe usage in food and pharma valves/seals.

Area of Application: Used in valves, flanges, pumps. Standards ensure tight sealing, minimal deformation, low wear, and chemical resistance.

5. PTFE Bearings, Bushes & Wear Parts
StandardDescription / ScopeImportance
ASTM D1894Friction testing of plastics.Ensures low-friction performance for moving parts.
ASTM D3702Wear testing of polymer composites.Evaluates bearing-grade PTFE under dynamic load.
ASTM D638 / D695Tensile and compressive strength.Verifies load-bearing capacity.
ISO 15527Creep performance under stress.Predicts long-term deformation in bearings.

Area of Application: Critical for mechanical assemblies, slides, guide strips. Standards ensure low wear rate, stable friction, and long life under load.

6. PTFE Insulation & Electrical Components
StandardDescription / ScopeImportance
UL 94Flammability rating of plastics.PTFE achieves V-0 — ensures fire safety.
IEC 60684 / ASTM D3294Electrical sleeving and tubing.Defines dielectric strength and voltage resistance.
ASTM D257Volume and surface resistivity.Ensures insulation reliability.
ASTM D150Dielectric constant and dissipation factor.Defines insulation efficiency for cables.

Area of Application: Used in wires, cables, PCB insulation, sensors. Standards ensure electrical safety, flame retardancy, and dielectric stability.

7. PTFE Coatings & Dispersion Grades
StandardDescription / ScopeImportance
ASTM D4894Dispersion PTFE resin specification.Ensures coating-grade PTFE uniformity.
ISO 12086-2Fluoropolymer dispersions.Standardizes dispersion composition and testing.
ASTM D2240Hardness testing.Checks coating surface hardness and wear resistance.
ASTM D3359Adhesion testing.Ensures proper bonding to metal or substrate.

Area of Application: Used in non-stick coatings, liners, and lubricating films. Standards guarantee film integrity, adhesion, and heat resistance.

8. PTFE Used in Food, Pharma & Medical Applications
Standard / RegulationScopeImportance
FDA 21 CFR 177.1550PTFE for food contact.Ensures safety for food and beverage contact.
EU 10/2011Food-contact plastics regulation.European compliance for food-grade PTFE.
USP Class VIBiocompatibility testing.Ensures suitability for medical and pharmaceutical use.
ISO 10993Biological evaluation of medical materials.Ensures non-toxicity and patient safety.

Area of Application: Used in food-grade seals, tubes, diaphragms, and medical devices. Standards guarantee chemical inertness, purity, and human safety.

9. Environmental and Safety Standards
Standard / RegulationScopeImportance
REACH / RoHSRestriction of hazardous substances.Ensures PTFE products are environmentally safe.
ISO 14001Environmental management system.Demonstrates sustainable production.
ISO 9001Quality management system.Ensures consistent manufacturing and traceability.

Area of Application: Used across all PTFE product lines for export, compliance, and certification.

Raw Material (PTFE Resin) Standards
Standard / CodeImportanceExamples / Description
ASTM D4894 / D4895Defines specifications and test methods for virgin and recycled PTFE resin.Ensures uniformity and quality of base material. Used by suppliers like Daikin, Chemours, 3M for powder qualification.
ISO 12086-1 / 12086-2International standards for PTFE and fluoropolymers.Ensures compatibility across global suppliers and processors.
ASTM D1457Specifies requirements for molded or extruded PTFE resin grades.Important for selecting correct type for molding, ram extrusion, or paste extrusion.
ASTM D4441Methods for testing PTFE resin flow rate.Used to ensure consistent extrusion and sintering performance.
PTFE Sheets, Rods, and Tubes (Semi-Finished Products)
Standard / CodeImportanceExamples / Description
ASTM D4895Specifies properties of PTFE compression-molded and ram-extruded shapes.Used for PTFE sheets, rods, and tubes.
ASTM D4745Defines specific gravity, tensile strength, elongation, and other mechanical tests.Used for quality inspection of semi-finished PTFE items.
ISO 13000-1Provides test methods for mechanical and physical properties of PTFE.Ensures product consistency for global trade.
DIN 4768 (Surface roughness)Checks surface finish quality of PTFE sheets used in sliding or sealing.Used in manufacture of bearing materials like Turcite.
Filled PTFE Grades (Compounds)
Standard / CodeImportanceExamples / Description
ASTM D4745Covers testing methods for mechanical and thermal properties of filled PTFE.Used for Bronze, Glass, Carbon, Graphite, MoS₂, and Pigmented PTFE.
ISO 12086-2Defines test procedures for PTFE compounds and blends.Helps compare global compound performance.
ASTM D4895 AnnexDescribes special requirements for filled PTFE performance consistency.Used by OEMs for mechanical seal rings, valve seats, bearing strips.
DIN 53479 / ISO 62Specifies water absorption and density testing.Ensures correct filler dispersion and integrity.
PTFE Seals, Gaskets & Valve Seat Standards (expanded)
Standard / CodeImportanceExamples / Description
ASTM F104Classification system for non-metallic gasket materials including PTFE.Used for selecting PTFE grades in sealing applications.
ASTM F37Measures leakage rate of gasket materials.Used for testing PTFE joint seal performance.
EN 13555Defines gasket parameters for flange design in PTFE-based gaskets.Essential for petrochemical and chemical industries.
API 622 / 607Fire-safe and fugitive emission standards for valve stem packing.Ensures PTFE seals meet safety and environmental standards.
Bearings, Wear Strips & Slideway Liners Standards (expanded)
Standard / CodeImportanceExamples / Description
ASTM D3702Test method for wear rate and coefficient of friction of PTFE materials.Used for validating bearing and slideway materials like Rulon, Turcite.
ASTM D4741Measures compressive creep of PTFE.Ensures load-bearing ability of PTFE wear parts.
ISO 7148-1 / 7148-2Specifies testing and design data for plain bearing materials including PTFE composites.Used by machinery and automotive OEMs.
DIN 31665Specifies PTFE bearing materials used in mechanical applications.Standard reference for European markets.
Electrical PTFE Insulation & Tubing (expanded)
Standard / CodeImportanceExamples / Description
ASTM D3032Test methods for PTFE-insulated electrical wire.Used for high-temperature cable insulation.
ASTM D1710Physical and electrical properties of PTFE resin for insulation.Ensures dielectric strength and insulation performance.
MIL-DTL-23053/12Military standard for PTFE heat-shrinkable tubing.Used in defence and aerospace wiring systems.
IEC 60684-3Requirements for PTFE heat shrink sleeving.Common in electronic and aerospace applications.
Testing & Quality Control Standards
StandardImportanceUse
ASTM D792Measures density and specific gravity of PTFE.Used in quality checks of all PTFE grades.
ASTM D638Tensile testing standard for plastics.Used to determine mechanical strength of PTFE products.
ASTM D2240Shore hardness testing of PTFE.Used for validation of moulded parts and seals.
ASTM D3418 / ISO 11357-1DSC testing for melting point and crystallinity.Ensures thermal consistency.
Chemical Resistance & Corrosion Applications
Standard / CodeImportanceUse
ASTM D543Evaluates chemical resistance of plastics including PTFE.Used in lining, piping, and tank applications.
ISO 175Measures mass & dimensional change after chemical exposure.Used in PTFE-lined fittings, pipes, and vessels.
ASTM G31Laboratory immersion corrosion test standard.Used for testing PTFE-lined steel assemblies.
Summary Table (At a Glance)
Product TypeKey Standards
PTFE ResinASTM D4894, ISO 12086
Sheets, Rods, TubesASTM D4745, ISO 13000
Filled PTFEASTM D4745, ISO 12086-2
Seals & GasketsASTM F104, EN 13555, API 622
Bearings / SlidewaysASTM D3702, ISO 7148
Electrical TubingASTM D3032, MIL-DTL-23053
Testing & QCASTM D638, D792, D2240, D3418
Chemical ResistanceASTM D543, ISO 175
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